Chapter 11. Sunflower lecithin as an alternative to soy lecithin: technological approaches to improving its rheological, sensory and functional properties

Authors

Anastasiia Demydova
Dmytro Motornyi Tavria State Agrotechnological University
https://orcid.org/0000-0002-4714-3450
Svitlana Panasyuk
Lutsk National Technical University
https://orcid.org/0000-0001-9734-3998
Yurii Hunko
Lutsk National Technical University
https://orcid.org/0000-0002-1441-9625
Keywords: sunflower lecithin, lecithin refining, resource-saving technologies, wet gum, color changes in lecithin, deodorization of lecithin, viscosity changes in lecithin, physicochemical properties of lecithin, lecithin quality parameters

Synopsis

Innovative approaches in food processing and sustainability

Soy lecithin remains the primary industrial source of lecithin; however, increasing concerns regarding its GMO origin have driven interest toward alternative sources. Among them, non-GMO sunflower lecithin has emerged as a high-quality and economically viable substitute. Despite its advantages, sunflower lecithin presents several technological drawbacks, including an intense flavor and odor, dark color, and high viscosity, which can lead to a plastic, non-flowable consistency.
The objective of this study was to develop technological strategies to produce decolorized, deodorized, and liquid sunflower lecithin. Deodorization was achieved by dissolving lecithin in ethyl alcohol at concentrations ≥ 40% (w/w), resulting in the complete removal of characteristic fatty, sweet, and nutty notes, while caramel and floral undertones became barely perceptible. This process led to the fractionation of lecithin into alcohol-soluble and alcohol-insoluble components. The use of absolute ethanol significantly reduced the yield of the alcohol-soluble fraction (from 23% to 13%).
Furthermore, it was found that the incorporation of specific diluents into wet gum prior to drying prevented the formation of a plastic consistency and ensured a stable liquid state during storage. Among the diluents tested, calcium salts proved to be the most effective. The optimal concentrations for maintaining lecithin liquidity were identified as follows: calcium acetate – 0.4%, calcium orthophosphate – 0.4%, and calcium chloride – 0.35%.
Decolorization conditions were also optimized, with the most effective parameters being 0.7% hydrogen peroxide (calculated as 100% H2O2), a temperature of 90 °C, and a treatment time of 120 minutes. Under these conditions, the color value of sunflower lecithin decreased from 18 to 4–6 mgJ2/100 cm3.
To evaluate the role of individual phospholipid groups in thermal darkening, fractionation was performed. Results indicated that phosphatidylcholines were most susceptible to darkening upon heating, followed by phosphatidylinositols, while phosphatidylserines and phosphatidylethanolamines exhibited the least color change. No correlation was observed between the sugar content of phospholipid fractions and their tendency to darken under thermal treatment.

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Author Biographies

Anastasiia Demydova, Dmytro Motornyi Tavria State Agrotechnological University

Doctor of Technical Sciences, Associate Professor
Department of Food Technology and Hotel and Restaurant Business
https://orcid.org/0000-0002-4714-3450
Corresponding author
anastasiia.demydova@tsatu.edu.ua

Svitlana Panasyuk, Lutsk National Technical University

PhD, Associate Professor
Department of Food Technology and Chemistry
https://orcid.org/0000-0001-9734-3998

Yurii Hunko, Lutsk National Technical University

PhD, Associate Professor
Department of Food Technology and Chemistry
https://orcid.org/0000-0002-1441-9625

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