

Innovative approaches in food processing and sustainability
Buckwheat and oats are traditional, though not the most popular, crops with strong environmental adaptability. The bioactive substances in buckwheat and oats have a positive impact on human health, including antioxidant and anti-inflammatory properties and the ability to prevent cancer. In this work, a comprehensive analysis of buckwheat and oat powders was carried out, including sieve analysis, infrared spectroscopy (IR spectroscopy), X-ray fluorescence analysis (XRF) and gas chromatography with mass spectrometry (GC/MS).
According to the results of sieve analysis, the highest content of fractions with a particle diameter of 1.1–0.5 mm was found: 41.76% for buckwheat powder and 52.56% for oat powder. The analysis of the IR spectra showed a similar chemical composition of both samples, including carbohydrates, proteins, fats and minerals. However, the buckwheat powder had a higher content of proteins and carbonyl compounds, and the oat powder had a higher content of polysaccharides. X-ray fluorescence analysis showed that both samples contain mainly C, H, P, S, K, Ca, Mn, Fe, Cu, Zn, but in different proportions. Buckwheat powder is characterized by a higher content of potassium and phosphorus, while oat powder has higher levels of calcium and manganese.
The GC/MS method was used to identify 15 bioactive compounds in buckwheat powder and 18 in oat powder. Sucrose, palmitic acid, linoleic acid and phytosterols (gamma-sitosterol, campesterol) were found in both samples. Buckwheat powder has a higher content of antioxidants, in particular γ-tocopherol, while oat powder contains steroidal compounds and oxazole derivatives that may affect lipid metabolism.
The study confirmed the unique nutritional profile of buckwheat and oat groats grown in Volyn. The results can be used in the field of functional food, pharmacology and nutrition to develop products with high biological activity.
PhD, Associate Professor
Department of Food Technologies and Chemistry
https://orcid.org/0000-0001-8952-5097
PhD, Associate Professor
Department of Food Technologies and Chemistry
https://orcid.org/0000-0001-9167-4876
Doctor of Pedagogic Sciences, Professor
Department of Food Technologies and Chemistry
https://orcid.org/0000-0002-1120-6165
Corresponding author
o.hulai@lntu.edu.ua
Ulian, T., Diazgranados, M., Pironon, S., Padulosi, S., Liu, U., Davies, L. et al. (2020). Unlocking plant resources to support food security and promote sustainable agriculture. Plants, People, Planet, 2 (5), 421–445. https://doi.org/10.1002/ppp3.10145
Molotoks, A., Smith, P., Dawson, T. P. (2020). Impacts of land use, population, and climate change on global food security. Food and Energy Security, 10 (1). https://doi.org/10.1002/fes3.261
Kopittke, P. M., Menzies, N. W., Wang, P., McKenna, B. A., Lombi, E. (2019). Soil and the intensification of agriculture for global food security. Environment International, 132, 105078. https://doi.org/10.1016/j.envint.2019.105078
Matías, J., Rodríguez, M. J., Carrillo-Vico, A., Casals, J., Fondevilla, S., Haros, C. M. et al. (2024). From ‘Farm to Fork': Exploring the Potential of Nutrient-Rich and Stress-Resilient Emergent Crops for Sustainable and Healthy Food in the Mediterranean Region in the Face of Climate Change Challenges. Plants, 13 (14), 1914. https://doi.org/10.3390/plants13141914
Kumar, L., Chhogyel, N., Gopalakrishnan, T., Hasan, M. K., Jayasinghe, S. L., Kariyawasam, C. S. et al. (2022). Climate change and future of agri-food production. Future Foods. Academic Press, 49–79. https://doi.org/10.1016/b978-0-323-91001-9.00009-8
Pingali, P. (2015). Agricultural policy and nutrition outcomes – getting beyond the preoccupation with staple grains. Food Security, 7 (3), 583–591. https://doi.org/10.1007/s12571-015-0461-x
Islam, S., Yu, W., Chen, W., Nyamsuren, N., Bayasgalankhuu, L., Achirafi, T. et al. (2024). Effect of Meteorological Factors on Maize Yield in Comoros. Journal of Life Sciences and Agriculture, 1 (2), 58–67. https://doi.org/10.62517/jlsa.202407211
Food and agriculture data. FAO. Available at: https://www.fao.org/faostat/en/#home
Li, L., Lietz, G., Seal, C. (2018). Buckwheat and CVD Risk Markers: A Systematic Review and Meta-Analysis. Nutrients, 10 (5), 619. https://doi.org/10.3390/nu10050619
Chen, J., Liu, Y., Liu, M., Guo, W., Wang, Y., He, Q. et al. (2023). Pangenome analysis reveals genomic variations associated with domestication traits in broomcorn millet. Nature Genetics, 55 (12), 2243–2254. https://doi.org/10.1038/s41588-023-01571-z
Dziadek, K., Kopeć, A., Pastucha, E., Piątkowska, E., Leszczyńska, T., Pisulewska, E. et al. (2016). Basic chemical composition and bioactive compounds content in selected cultivars of buckwheat whole seeds, dehulled seeds and hulls. Journal of Cereal Science, 69, 1–8. https://doi.org/10.1016/j.jcs.2016.02.004
Raguindin, P. F., Adam Itodo, O., Stoyanov, J., Dejanovic, G. M., Gamba, M., Asllanaj, E. et al. (2021). A systematic review of phytochemicals in oat and buckwheat. Food Chemistry, 338, 127982. https://doi.org/10.1016/j.foodchem.2020.127982
Jin, J., Ohanenye, I. C., Udenigwe, C. C. (2020). Buckwheat proteins: functionality, safety, bioactivity, and prospects as alternative plant-based proteins in the food industry. Critical Reviews in Food Science and Nutrition, 62 (7), 1752–1764. https://doi.org/10.1080/10408398.2020.1847027
Bhinder, S., Kaur, A., Singh, B., Yadav, M. P., Singh, N. (2020). Proximate composition, amino acid profile, pasting and process characteristics of flour from different Tartary buckwheat varieties. Food Research International, 130, 108946. https://doi.org/10.1016/j.foodres.2019.108946
Bobkov, S.; Zhou, M. (Ed.) (2016). Biochemical and technological properties of buckwheat grains. Molecular breeding and nutritional aspects of buckwheat. Academic Press, 423–440. https://doi.org/10.1016/B978-0-12-803692-1.00034-1
Gao, J., Kreft, I., Chao, G., Wang, Y., Liu, X., Wang, L. et al. (2016). Tartary buckwheat ( Fagopyrum tataricum Gaertn.) starch, a side product in functional food production, as a potential source of retrograded starch. Food Chemistry, 190, 552–558. https://doi.org/10.1016/j.foodchem.2015.05.122
Das, S. K., Avasthe, R., Ghosh, G. K., Dutta, S. Kr. (2019). Pseudocereal Buckwheat With Potential Anticancer Activity. Bulletin of Pure & Applied Sciences-Botany, 38 (2), 93. https://doi.org/10.5958/2320-3196.2019.00013.2
Morales, D., Miguel, M., Garcés-Rimón, M. (2020). Pseudocereals: a novel source of biologically active peptides. Critical Reviews in Food Science and Nutrition, 61 (9), 1537–1544. https://doi.org/10.1080/10408398.2020.1761774
Leszczyńska, D., Wirkijowska, A., Gasiński, A., Średnicka-Tober, D., Trafiałek, J., Kazimierczak, R. (2023). Oat and Oat Processed Products – Technology, Composition, Nutritional Value, and Health. Applied Sciences, 13 (20), 11267. https://doi.org/10.3390/app132011267
Sterna, V., Zute, S., Brunava, L. (2016). Oat Grain Composition and its Nutrition Benefice. Agriculture and Agricultural Science Procedia, 8, 252–256. https://doi.org/10.1016/j.aaspro.2016.02.100
Kruma, Z., Tomsone, L., Galoburda, R., Straumite, E., Kronberga, A., Åssveen, M. (2016). Total phenols and antioxidant capacity of hull-less barley and hull-less oats., Agronomy Research, 14, (Special Issue II), Saku, 1361–1371.
Martínez-Villaluenga, C., Peñas, E. (2017). Health benefits of oat: current evidence and molecular mechanisms. Current Opinion in Food Science, 14, 26–31. https://doi.org/10.1016/j.cofs.2017.01.004
de Oliveira Maximino, J. V., Barros, L. M., Pereira, R. M., de Santi, I. I., Aranha, B. C., Busanello, C. et al. (2020). Mineral and Fatty Acid Content Variation in White Oat Genotypes Grown in Brazil. Biological Trace Element Research, 199 (3), 1194–1206. https://doi.org/10.1007/s12011-020-02229-1
Deng, G., Vu, M., Korbas, M., Bondici, V. F., Karunakaran, C., Christensen, D., Bart Lardner, H. A., Yu, P. (2023). Distribution of micronutrients in Arborg oat (Avena sativa L.) using synchrotron X-ray fluorescence imaging. Food Chemistry, 421, 135661. https://doi.org/10.1016/j.foodchem.2023.135661
Dudarev, I., Zabrodotska, L., Satsiuk, V., Taraymovich, I., Olkhovsky, V. (2020). Research on seed separation process on a gravity-cascade separator. INMATEH Agricultural Engineering, 62 (3), 173–180. https://doi.org/10.35633/inmateh-62-18
Hulai, O. I., Shemet, V. Ya., Klimovych, O. S. (2023). Chromatographic Determination of the Chemical Composition of Apple Chips Extract. Methods and Objects of Chemical Analysis, 18 (1), 33–41. https://doi.org/10.17721/moca.2023.33-41

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